Graft Copolymerization by Radiation.

Radiation-Induced Graft Copolymerization of Acrylonitrile onto Kappa-Carrageenan

The monomer, acrylonitrile, was graft copolymerized onto kappa-carrageenan (kC) using γ-rays as initiator. The reactions were carried out in a homogenous aqueous medium. After removal of the homopolymer, the graft copolymer was characterized by FTIR spectroscopy. A plausible mechanism of grafting has also been suggested. The effect of various factors affecting on grafting, i.e. dose of δ-rays a...

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods

Gamma Radiation-Induced Graft Copolymerization of Styrene onto Poly(ethyleneTerephthalate) Films

Gamma radiation-induced graft copolymerization of styrene onto poly(ethylene terephthalate) (PET) films was studied using simultaneous irradiation technique. The effects of grafting conditions on the degree of grafting were investigated. The grafting conditions include monomer concentration, irradiation dose, dose rate, and the type of solvent. Moreover, the effect of the addition of crosslinki...

Gamma Radiation Induced Graft Copolymerization of Typical Monomers onto Poly (3-hydroxybutyrate)

The preparation of several graft copolymers obtained by radiation induced graft copolymerization of typical monomers onto poly (3hydroxybutyrate) is reviewed. The general mechanisms by which graft copolymerization reaction proceed under various irradiation conditions are described. Main attention is given to the structure, properties, synthesis and characterization of the graft product, as well...

Cation Exchange Membranes by Radiation-Induced Graft Copolymerization of Styrene onto PFA Copolymer Films. III. Thermal Stability of the Membranes

Thermal stability of cation exchange, PFA-g-polystyrene sulfonic acid membranes prepared by radiation-induced graft copolymerization of styrene onto PFA films followed by sulfonation was studied by thermal gravimetric analysis (TGA) and oven heat treatment. The tested samples included original and grafted PFA films as reference materials. All the membranes showed multistep decomposition pattern...